The “it” couple in Hollywood was Brangelina. The two award-winning actors began dating in 2006 after collaborating on the previous Mr. and Mrs. Smith movie. The tabloids went wild with their scandalous romance. Jolie was charged with orchestrating Brad Pitt and Jennifer Aniston’s divorce in 2005. It wasn’t until 2014 that they made their union legal at their Chateau Miraval estate in Correns, France. Three biological children and three children they adopted overseas made up the Brangelina brood throughout their 12-year relationship. Sadly, their marriage dissolved in 2016. The price tag on their widely reported divorce was almost $400 million.